Asymmetric Magnesium-Catalyzed Hydroboration by Metal-Ligand Cooperative Catalysis was written by Falconnet, Alban;Magre, Marc;Maity, Bholanath;Cavallo, Luigi;Rueping, Magnus. And the article was included in Angewandte Chemie, International Edition in 2019.Electric Literature of C40H26O2 The following contents are mentioned in the article:
Asym. catalysis with readily available, cheap, and nontoxic alk. earth metal catalysts represents a sustainable alternative to conventional synthesis methodologies. In this context, the authors describe the development of a 1st Mg(II)-catalyzed enantioselective hydroboration providing the products with excellent yields and enantioselectivities. NMR spectroscopy studies and DFT calculations provide insights into the reaction mechanism and the origin of the enantioselectivity which can be explained by a metal-ligand cooperative catalysis pathway involving a noninnocent ligand. This study involved multiple reactions and reactants, such as (R)-[1,3′:1′,1”:3”,1”’-Quaternaphthalene]-2′,2”-diol (cas: 851615-07-1Electric Literature of C40H26O2).
(R)-[1,3′:1′,1”:3”,1”’-Quaternaphthalene]-2′,2”-diol (cas: 851615-07-1) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Electric Literature of C40H26O2
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts