Category: 63012-03-3

In ,Organic Letters included an article by Pan, Ting; Shi, Pan; Chen, Bo; Zhou, Da-Gang; Zeng, Ya-Li; Chu, Wen-Dao; He, Long; Liu, Quan-Zhong; Fan, Chun-An. COA of Formula: C13H11ClO. The article was titled 《CuH-Catalyzed Asymmetric 1,6-Conjugate Reduction of p-Quinone Methides: Enantioselective Synthesis of Triarylmethanes and 1,1,2-Triarylethanes》. The information in the text is summarized as follows:

The first copper hydride (CuH)-catalyzed asym. 1,6-conjugate reduction of p-quinone methides is reported. This protocol provides a new method to access a variety of triarylmethanes and 1,1,2-triarylethanes in good yields with excellent enantioselectivities and broad functional group tolerance. The results came from multiple reactions, including the reaction of (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3COA of Formula: C13H11ClO)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The joining of a fatty acid to glycerol to form a triacylglycerol removes the −OH from the carboxy end of the fatty acid.COA of Formula: C13H11ClO

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The author of 《Efficient approach to carbinol derivatives through palladium-catalyzed base-free addition of aryltriolborates to aldehydes》 were Hu, Kun; Ye, Pengqing; Zhen, Qianqian; Yao, Xinrong; Xu, Tong; Shao, Yinlin; Chen, Jiuxi. And the article was published in Molecules in 2017. Reference of (3-Chlorophenyl)(phenyl)methanol The author mentioned the following in the article:

Palladium-catalyzed base-free addition of aryltriolborates to aldehydes was developed, led to a wide range of carbinol derivatives in good to excellent yields. The efficiency of this transformation was demonstrated by compatibility with a wide range of functional groups. The present synthetic route to carbinol derivatives was readily scaled up to gram quantity without difficulty. Thus, this method represented a simple and practical procedure to access carbinol derivatives The experimental process involved the reaction of (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Reference of (3-Chlorophenyl)(phenyl)methanol)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The joining of a fatty acid to glycerol to form a triacylglycerol removes the −OH from the carboxy end of the fatty acid.Reference of (3-Chlorophenyl)(phenyl)methanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2018,RSC Advances included an article by Li, Yuting; Zhu, Yan; Tu, Guangliang; Zhang, Jingyu; Zhao, Yingsheng. Formula: C13H11ClO. The article was titled 《Silver-catalyzed direct benzylation of acetanilide: a highly efficient approach to unsymmetrical triarylmethanes》. The information in the text is summarized as follows:

A highly efficient silver-catalyzed dibenzylation of acetanilides by employing the benzhydrol derivatives as the coupling partners to yield triphenylmethane derivatives was developed. Various functional groups were tolerated, leading to the corresponding products in moderate to good yields. Preliminary exptl. results indicated that the silver ions activate the arene rings and the strong acid TfOH provides the carbocations. The experimental part of the paper was very detailed, including the reaction process of (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Formula: C13H11ClO)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains.Formula: C13H11ClO The joining of a fatty acid to glycerol to form a triacylglycerol removes the −OH from the carboxy end of the fatty acid.

Referemce:
Alcohol – Wikipedia,
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《Benzoyl cellulose beads in the pure polymeric form as a new powerful sorbent for the chromatographic resolution of racematesã€?was published in Chirality in 1991. These research results belong to Francotte, Eric; Wolf, Romain M.. Category: alcohols-buliding-blocks The article mentions the following:

Cellulose-based stationary phases are known to be very efficient and versatile chiral sorbents for the chromatog. resolution of racemates. Except for microcrystalline cellulose triacetate, basically all other cellulose-based phases are prepared by coating of �0% weight polymer on a wide-pore silica gel used as a carrier. Benzoyl cellulose beads were in the pure polymeric form (without inorganic carrier) from an emulsion of the organic polymer. The new material was characterized fully and used as a chiral stationary phase for the resolution of various classes of racemic compounds such as benzylic alcs. or acetate derivatives of aliphatic alcs. and diols. The structural variety of the separated solutes as well as the irrational influence of the aromatic substituent in different classes of aryl compounds suggest that multiple interaction sites are involved in the complexation, making a prediction of the separation difficult. The benzoyl cellulose beads exhibit a very high loading capacity, which is particularly useful for preparative purposes, as shown for selected examples. The experimental process involved the reaction of (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Category: alcohols-buliding-blocks)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group. Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.Category: alcohols-buliding-blocks

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Alcohol – Wikipedia,
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Hu, Liangzhen; Hussain, Muhammad Ijaz; Deng, Qingfu; Liu, Qing; Feng, Yangyang; Zhang, Xiaohui; Xiong, Yan published an article on January 11 ,2019. The article was titled 《I2/Li2CO3-promoted cyanation of diarylalcohols through a dual activation processã€? and you may find the article in Tetrahedron.Reference of (3-Chlorophenyl)(phenyl)methanol The information in the text is summarized as follows:

One-step base promoted strategy for cyanation of α,α-diaryl alcs. has been developed under mild and transition metal-free conditions. This method provides a straightforward and facile way towards the synthesis of β,γ-unsaturated nitriles and α-phenylnitiriles from α-vinyl carbinols and α,α-diaryl methanols, resp., up to 99% yield. Moreover, various azides and ethers could also be accessed from their resp. nucleophiles under standard reaction conditions. In addition to this study using (3-Chlorophenyl)(phenyl)methanol, there are many other studies that have used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Reference of (3-Chlorophenyl)(phenyl)methanol) was used in this study.

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group.Reference of (3-Chlorophenyl)(phenyl)methanol Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.

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Alcohol – Wikipedia,
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In 1996,Chirality included an article by Maier, Norbert M.; Uray, Georg. Safety of (3-Chlorophenyl)(phenyl)methanol. The article was titled 《Diphenylethanediamine (DPEDA) as chiral selector: VII. Efficient HPLC resolution of a series of underivatized diarylcarbinols on a chiral stationary phase based on C5-amide-bonded N-3,5-dinitrobenzoyl-DPEDAã€? The information in the text is summarized as follows:

Fast and efficient baseline separation of asym. substituted diarylmethanols and 1,1-diarylethanols was achieved on an endcapped, amide-linked N-3,5-dinitrobenzoylated, (R,R)-1,2-diphenyl-1,2-ethanediamine-derived chiral stationary phase (CSP). Optimal enantioselectivities on this CSP were obtained using 1% 2-propanol in n-heptane as the mobile phase. Enantiorecognition was found to governed by π-basicity and the substitution pattern of the aromatic substituents. In the experiment, the researchers used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Safety of (3-Chlorophenyl)(phenyl)methanol)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The creation of a peptide bond to link two amino acids to make a protein removes the −OH from the carboxy group of one amino acid.Safety of (3-Chlorophenyl)(phenyl)methanol

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Alcohol – Wikipedia,
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Application of 63012-03-3On March 20, 2014, Farhadi, Saeed; Jahanara, Kosar published an article in Cuihua Xuebao. The article was 《ZnAl2O4@SiO2 nanocomposite catalyst for the acetylation of alcohols, phenols and amines with acetic anhydride under solvent-free conditionsã€? The article mentions the following:

A ZnAl2O4@SiO2 nanocomposite was prepared from metal nitrates and tetra-Et orthosilicate by the sol-gel process, and characterized by X-ray diffraction, Fourier transform IR, transmission electron microscopy, and N2 adsorption-desorption measurements. The nanocomposite was tested as a heterogeneous catalyst for the acetylation of alcs., phenols, and amines under solvent-free conditions. Under optimized conditions, efficient acetylation of these substrates with acetic anhydride over the ZnAl2O4@SiO2 nanocomposite was obtained. Acetylation of anilines and primary aliphatic amines proceeded rapidly at room temperature, while the reaction time was longer for the acetylation of alcs. and phenols, showing that an amine NH2 group can be selectively acetylated in the presence of alc. or phenolic OH groups. The catalyst can be reused without obvious loss of catalytic activity. The catalytic activity of the ZnAl2O4@SiO2 nanocomposite was higher than that of pure ZnAl2O4. The method gives high yields, and is clean, cost effective, compatible with substrates having other functional groups and it is suitable for practical organic synthesis. The experimental part of the paper was very detailed, including the reaction process of (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Application of 63012-03-3)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group.Application of 63012-03-3 Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Microwave-assisted nickel(II) acetylacetonate-catalyzed arylation of aldehydes with arylboronic acidsã€?was written by Chen, Wen; Baghbanzadeh, Mostafa; Kappe, C. Oliver. Synthetic Route of C13H11ClO And the article was included in Tetrahedron Letters on April 6 ,2011. The article conveys some information:

Applying sealed vessel microwave heating at 180 °C in toluene the arylation of aromatic and aliphatic aldehydes with arylboronic acids using 1-2 mol % of Ni(acac)2 as a catalyst can be performed efficiently within 10-30 min providing the desired diarylmethanols or benzyl alcs. in good yields. In the experimental materials used by the author, we found (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Synthetic Route of C13H11ClO)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group.Synthetic Route of C13H11ClO Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Recommanded Product: (3-Chlorophenyl)(phenyl)methanolOn November 30, 2011 ,《Lithium perchlorate-nitromethane-promoted alkylation of anilines with arylmethanolsã€?appeared in Molecular Diversity. The author of the article were Zhou, Jun; Mao, Hai-Feng; Wang, Lu; Zou, Jian-Ping; Zhang, Wei. The article conveys some information:

A new application of LiClO4-nitromethane (LPNM) for the formation of aromatic C-N and C-C bonds is introduced. LPNM-promoted reactions of anilines with diarylmethanols selectively generate N-alkylated anilines or mono and double Friedel-Crafts alkylation products under different conditions by changing the reaction time, reaction temperature, and the ratio of the reactants. This method does not require the use of transition metal catalysts to prepare alkylated aniline derivatives In the part of experimental materials, we found many familiar compounds, such as (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Recommanded Product: (3-Chlorophenyl)(phenyl)methanol)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains.Recommanded Product: (3-Chlorophenyl)(phenyl)methanol The joining of a fatty acid to glycerol to form a triacylglycerol removes the −OH from the carboxy end of the fatty acid.

Referemce:
Alcohol – Wikipedia,
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Reference of (3-Chlorophenyl)(phenyl)methanolOn March 9, 2000, Ohkuma, Takeshi; Koizumi, Masatoshi; Ikehira, Hideyuki; Yokozawa, Tohru; Noyori, Ryoji published an article in Organic Letters. The article was 《Selective Hydrogenation of Benzophenones to Benzhydrols. Asymmetric Synthesis of Unsymmetrical Diarylmethanols》. The article mentions the following:

Trans-RuCl2[P(C6H4-4-CH3)3]2(NH2CH2CH2NH2) acts as a highly effective precatalyst for the hydrogenation of a variety of benzophenone derivatives to benzhydrols that proceeds smoothly at 8 atm and 23-35 °C in 2-propanol containing t-C4H9OK with a substrate/catalyst ratio of 2000-20000. Use of a BINAP/chiral diamine Ru complex effects asym. hydrogenation of various ortho-substituted benzophenones and benzoylferrocene to chiral diarylmethanols with consistently high ee. In the experiment, the researchers used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Reference of (3-Chlorophenyl)(phenyl)methanol)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group.Reference of (3-Chlorophenyl)(phenyl)methanol Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts