Category: 12080-32-9

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Synthesis, Coordination and Electrochemistry of a Ferrocenyl-Tagged Aminobisphosphane Ligand, published in 2021-09-24, which mentions a compound: 12080-32-9, Name is Dichloro(1,5-cyclooctadiene)platinum(II), Molecular C8H12Cl2Pt, Quality Control of Dichloro(1,5-cyclooctadiene)platinum(II).

Group 10 element diphosphine square planar complexes [FcN(CH2PPh2)2MY2] (Fc = ferrocenyl; M = Ni, Pd, Pt; Y = Cl, Br), Group 11 tetraphosphine tetrahedral complexes [[FcN(CH2PPh2)2]2M]X (M = Cu, Ag, Au; X = BF4, SbF6) and gold binuclear complexes [FcN(CH2PPh2AuCl)2], [FcN(CH2PPh2)2Au]2[SbF6]2 were prepared and examined for their redox activity. Introducing a ferrocene moiety into a mol. results in the incorporation of a metal center and a redox active moiety. The ligand FcN(CH2PPh2)2 (1) was prepared by alkylation of ferrocenamine FcNH2 with hydroxymethylphosphine HOCH2PPh2 and converted to diselenide FcN(CH2P(Se)Ph2)2 (1-Se) for crystallog. identification. Furthermore, a pair of open and cyclic digold(I) complexes containing bis-phosphane 1 as a P,P-bridging ligand, were isolated. Ligand 1, the corresponding phosphane selenide 1-Se and all complexes (except for the poorly soluble [(μ(P,P’)-1)2Au2][SbF6] and unstable [Ag(1-κ2P,P’)2][SbF6]) were further analyzed by cyclic voltammetry.

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SDS of cas: 12080-32-9. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Laser-induced deposition of plasmonic Ag and Pt nanoparticles, and periodic arrays. Author is Mamonova, Daria V.; Vasileva, Anna A.; Petrov, Yuri V.; Danilov, Denis V.; Kolesnikov, Ilya E.; Kalinichev, Alexey A.; Bachmann, Julien; Manshina, Alina A..

Surfaces functionalized with metal nanoparticles (NPs) are of great interest due to their wide potential applications in sensing, biomedicine, nanophotonics, etc. However, the precisely controllable decoration with plasmonic nanoparticles requires sophisticated techniques that are often multistep and complex. Here, we present a laser-induced deposition (LID) approach allowing for single-step surface decoration with NPs of controllable composition, morphol., and spatial distribution. The formation of Ag, Pt, and mixed Ag-Pt nanoparticles on a substrate surface was successfully demonstrated as a result of the LID process from com. available precursors. The deposited nanoparticles were characterized with SEM, TEM, EDX, X-ray diffraction, and UV-VIS absorption spectroscopy, which confirmed the formation of crystalline nanoparticles of Pt (3-5 nm) and Ag (ca. 100 nm) with plasmonic properties. The advantageous features of the LID process allow us to demonstrate the spatially selective deposition of plasmonic NPs in a laser interference pattern, and thereby, the formation of periodic arrays of Ag NPs forming diffraction grating.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Bimetallic Platinum Group Complexes of a Macrocyclic Pyrazolate/NHC Hybrid Ligand.Safety of Dichloro(1,5-cyclooctadiene)platinum(II).

Authors present the synthesis, structural characterization, and photophys. properties of dinuclear PdII and PtII-NHC complexes Pd2L(PF6)2 and Pt2L(PF6)2 based on a macrocyclic calix[4]imidazolylidene[2]pyrazolate ligand obtained by in situ deprotonation of the tetraimidazolium salt H6L(PF6)4. The PtII congener was also prepared by transmetalation from previously published AgI pillarplex Ag8L2(PF6)4. NMR spectroscopy (1H, 13C, 195Pt) combined with SC-XRD studies elucidated the structure of the PdII and PtII complexes in the solid state and in solution The d8 metal ions of both congeners are coordinated in a slightly distorted square-planar arrangement. Similar to the previously reported NiII complex Ni2L(PF6)2, the heavier metal homologues adopt a bent, saddle-shaped structure. As observed for structurally similar PtII complexes in solution, bimetallic Pt2L(PF6)2 showed photoluminescence in the blue region. In the solid state, emission was observed at a similar energy with unusually short lifetimes compared to other monometallic PtII complexes. DFT and TDDFT studies shed light on the nature of the most bathochromic transitions, suggesting a significant pyrazolate- and NHC-centered π-π* character.

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Electric Literature of C8H12Cl2Pt. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Transmetalation Reactions of Aromatic Dilithionickelole: Synthesis of Heterobimetallic Complexes Featuring Metalloles as Diene Ligands. Author is Huang, Zhe; Zheng, Yu; Zhong, Mingdong.

Transmetalation of dilithionickelole I (1) with metal sources [MCl2Ln] afforded nickel-coordinated metallacycles II [2-6; MLn = Mg(THF)2, AlCl(THF), ScCp(THF), LuCp*ClLi(THF)3, Pt(COD)]. The aromatic metallole dianions are important metallaarom. compounds because of their various reactivities and extensive synthetic applications. Herein we report the reactions of dilithionickelole with MgCl2, EtAlCl2, Cp*ScCl2, Cp*LuCl2 and Pt(COD)Cl2 (COD = 1,5-cyclooctadiene) affording a series of Ni/M heterobimetallic complexes of the general formula [(η4-C4R4M)Ni(COD)], in which the metalloles act as diene ligands, as suggested by single-crystal X-ray, NMR and theor. analyses. In these reactions, two electrons of the nickelole dianion transferred to Ni, representing different reactivity compared with main-group metallole dianions.

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Recommanded Product: 12080-32-9. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Synthesis and structure of thienyl Fischer carbene complexes of PtII for application in alkyne hydrosilylation. Author is Lamprecht, Zandria; Malan, Frederick P.; Lotz, Simon; Bezuidenhout, Daniela I..

Transmetalation of Group 6 thienylene Fischer carbene complexes to Pt(II) precursors yielded new examples of neutral Pt(II) bisethoxycarbene complexes with either 2-thienyl (T) or 5-thieno[2,3-b]thienylene (TT) carbene substituents. The use of analogous aminocarbene group 6 precursors proceeded to give isomeric Pt(II) product mixtures where the resultant bisaminocarbene ligands displayed different orientations due to restricted rotation around the Pt-aminocarbene bond caused by the sterically demanding TT substituents. The well-defined Pt(II) ethoxycarbene complexes were screened as catalyst precursors in the benchmark hydrosilylation reaction employing phenylacetylene and triethylsilane substrates. Marked selectivity for the β-E isomer (E)-triethyl(styryl)silane was observed, and the (pre)catalysts proved recyclable, active in solvent-free reactions, and displaying a high alkyne functional group tolerance.

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SDS of cas: 12080-32-9. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Cyclometalated Platinum(II) Complexes with Mesoionic Dibenzofuranyl-1,2,3-triazol-4-ylidene Ligands: Synthesis, Characterization and Photophysical Properties. Author is Soellner, Johannes; Strassner, Thomas.

Platinum(II) complexes with mesoionic C-C*-cyclometalating 1,2,3-triazolylidene ligands are highly efficient phosphorescent emitters. Herein we report a series of this type bearing dibenzofuranyl-substituted carbenes along with different β-diketonate auxiliary ligands. They show luminescence in the green region of the visible spectrum and quantum yields of up to 78% at room temperature The proposed mol. structures were verified by NMR spectroscopy and x-ray diffraction experiments which prove the formation of the mesoionic carbene. Addnl., DFT calculations and cyclic voltammetry measurements were used to rationalize the observed photophys. properties of the reported complexes.

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Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Multinuclear Ag Clusters Sandwiched by Pt Complex Units: Fluxional Behavior and Chiral-at-Cluster Photoluminescence.HPLC of Formula: 12080-32-9.

Multinuclear Ag clusters sandwiched by Pt complex units were synthesized and characterized by single crystal X-ray diffraction and NMR studies. The sandwich-shaped multinuclear Ag complexes showed two different types of fluxional behavior in solution: rapid slippage of Pt complex units on the Ag3 core and a reversible demetalation-metalation reaction by the treatment with Cl anion and Ag ion, resp. The Ag2 complex obtained by demetalation reaction from the Ag3 complex displayed U to Z isomerization. These multinuclear Ag complexes showed strong photoluminescence whose properties depended on the existence of Pt→Ag dative bonds. The Ag3 complex, identified to be “”chiral-at-cluster””, was optically resolved by the formation of a diastereomeric salt with a chiral anion. The enantiomers show CD (CD) and circularly polarized luminescence (CPL) properties which is unprecedented for compounds based on a chiral sandwich structure. Theor. calculations allow to understand their structural features and photophys. properties.

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Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 12080-32-9, is researched, SMILESS is C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-], Molecular C8H12Cl2PtJournal, Applied Organometallic Chemistry called Platinum(II) complexes bearing bulky Schiff base ligands anchored onto mesoporous SBA-15 supports as efficient catalysts for hydrosilylation, Author is Huo, Yingpeng; Hu, Jiwen; Lin, Shudong; Ju, Xingming; Wei, Yanlong; Huang, Zhenzhu; Hu, Yangfei; Tu, Yuanyuan, the main research direction is silica supported naphthalenolimine Schiff base platinum cyclooctadiene preparation catalyst; bulky Schiff base anchored mesoporous SBA 15 catalyst hydrosilylation; hydrosilylation terminal alkene styrene silane regioselectivity catalyst preparation.Formula: C8H12Cl2Pt.

Reported herein is an easy-to-prepare novel heterogeneous catalyst of platinum complexes bearing binary ligands of bidentate naphthalenolimine and cyclo-1,5-octadiene that are anchored onto mesoporous silica SBA-15. The presence of the binary ligands not only stabilized the platinum, but also enabled the platinum atoms to form nanoclusters with diameters of ca 1 nm, and led to high platinum loading (8.69 wt%). Moreover, the platinum catalyst exhibited high catalytic activity towards hydrosilylation of terminal alkenes and styrene with silanes under mild and solvent-free conditions, with excellent regioselectivity.

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Related Products of 12080-32-9. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Laser-induced deposition of plasmonic Ag and Pt nanoparticles, and periodic arrays. Author is Mamonova, Daria V.; Vasileva, Anna A.; Petrov, Yuri V.; Danilov, Denis V.; Kolesnikov, Ilya E.; Kalinichev, Alexey A.; Bachmann, Julien; Manshina, Alina A..

Surfaces functionalized with metal nanoparticles (NPs) are of great interest due to their wide potential applications in sensing, biomedicine, nanophotonics, etc. However, the precisely controllable decoration with plasmonic nanoparticles requires sophisticated techniques that are often multistep and complex. Here, we present a laser-induced deposition (LID) approach allowing for single-step surface decoration with NPs of controllable composition, morphol., and spatial distribution. The formation of Ag, Pt, and mixed Ag-Pt nanoparticles on a substrate surface was successfully demonstrated as a result of the LID process from com. available precursors. The deposited nanoparticles were characterized with SEM, TEM, EDX, X-ray diffraction, and UV-VIS absorption spectroscopy, which confirmed the formation of crystalline nanoparticles of Pt (3-5 nm) and Ag (ca. 100 nm) with plasmonic properties. The advantageous features of the LID process allow us to demonstrate the spatially selective deposition of plasmonic NPs in a laser interference pattern, and thereby, the formation of periodic arrays of Ag NPs forming diffraction grating.

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Category: alcohols-buliding-blocks. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Phosphorus and Arsenic Atom Transfer to Isocyanides to Form π-Backbonding Cyanophosphide and Cyanoarsenide Titanium Complexes. Author is Reinholdt, Anders; Jafari, Mehrafshan G.; Sandoval-Pauker, Christian; Ballestero-Martinez, Ernesto; Gau, Michael R.; Driess, Matthias; Pinter, Balazs; Mindiola, Daniel J..

Decarbonylation along with E atom transfer from Na(OCE) (E = P, As) to an isocyanide coordinated to the tetrahedral TiII complex [(TptBu,Me)TiCl], yielded the [(TptBu,Me)Ti(η3-ECNAd)] species (Ad = 1-adamantyl, TptBu,Me- = hydrotris(3-tert-butyl-5-methylpyrazol-1-yl)borate). In the case of E = P, the cyanophosphide ligand displays nucleophilic reactivity toward Al(CH3)3; moreover, its bent geometry hints to a reduced Ad-NCP3- resonance contributor. The analogous and rarer mono-substituted cyanoarsenide ligand, Ad-NCAs3-, shows the same unprecedented coordination mode but with shortening of the N:C bond. As opposed to TiII, VII fails to promote P atom transfer to AdNC, yielding instead [(TptBu,Me)V(OCP)(CNAd)]. Theor. studies revealed the rare ECNAd moieties to be stabilized by π-backbonding interactions with the former TiII ion, and their assembly to most likely involve a concerted E atom transfer between Ti-bound OCE- to AdNC ligands when studying the reaction coordinate for E = P.

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