Extracurricular laboratory: Synthetic route of 12080-32-9

Although many compounds look similar to this compound(12080-32-9)Quality Control of Dichloro(1,5-cyclooctadiene)platinum(II), numerous studies have shown that this compound(SMILES:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Synthesis, Coordination and Electrochemistry of a Ferrocenyl-Tagged Aminobisphosphane Ligand, published in 2021-09-24, which mentions a compound: 12080-32-9, Name is Dichloro(1,5-cyclooctadiene)platinum(II), Molecular C8H12Cl2Pt, Quality Control of Dichloro(1,5-cyclooctadiene)platinum(II).

Group 10 element diphosphine square planar complexes [FcN(CH2PPh2)2MY2] (Fc = ferrocenyl; M = Ni, Pd, Pt; Y = Cl, Br), Group 11 tetraphosphine tetrahedral complexes [[FcN(CH2PPh2)2]2M]X (M = Cu, Ag, Au; X = BF4, SbF6) and gold binuclear complexes [FcN(CH2PPh2AuCl)2], [FcN(CH2PPh2)2Au]2[SbF6]2 were prepared and examined for their redox activity. Introducing a ferrocene moiety into a mol. results in the incorporation of a metal center and a redox active moiety. The ligand FcN(CH2PPh2)2 (1) was prepared by alkylation of ferrocenamine FcNH2 with hydroxymethylphosphine HOCH2PPh2 and converted to diselenide FcN(CH2P(Se)Ph2)2 (1-Se) for crystallog. identification. Furthermore, a pair of open and cyclic digold(I) complexes containing bis-phosphane 1 as a P,P-bridging ligand, were isolated. Ligand 1, the corresponding phosphane selenide 1-Se and all complexes (except for the poorly soluble [(μ(P,P’)-1)2Au2][SbF6] and unstable [Ag(1-κ2P,P’)2][SbF6]) were further analyzed by cyclic voltammetry.

Although many compounds look similar to this compound(12080-32-9)Quality Control of Dichloro(1,5-cyclooctadiene)platinum(II), numerous studies have shown that this compound(SMILES:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts