Category: 12080-32-9

Name: Dichloro(1,5-cyclooctadiene)platinum(II). Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Synthesis and Structures of Stable PtII and PtIV Alkylidenes: Evidence for π-Bonding and Relativistic Stabilization. Author is Lapierre, Etienne A.; Piers, Warren E.; Lin, Jian-Bin; Gendy, Chris.

Isolable cationic PtII and PtIV alkylidenes, proposed intermediates in catalytic organic transformations, are reported. The bonding in these species was probed by exptl., structural, spectroscopic, electrochem. and computational methods, providing direct evidence for π-bonding, the often-theorized relativistic stabilization of these species, and the influence of oxidation state.

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Synthetic Route of C8H12Cl2Pt. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Vapochromic luminescent proton conductors: switchable vapochromism and proton conduction of luminescent Pt(II) complexes with proton-exchangeable sites. Author is Kobayashi, Atsushi; Imada, Shin-ichiro; Shigeta, Yasuhiro; Nagao, Yuki; Yoshida, Masaki; Kato, Masako.

Two luminescent and highly proton-conductive Pt(II) complexes [PtCl(tpypy)]Cl and [PtCl(tpypyH)]Cl2 (1 and 1·HCl, resp.; tpypy = 2,2′: 6′,2”-terpyridine-4′,4”’-pyridine) were successfully synthesized. X-ray anal. revealed that the intermol. Pt···Pt interaction was ineffective in the monohydrated form of 1·H2O but effective in dihydrate and hexahydrate forms, 1·HCl·nH2O (n = 2 and 6). Yellow luminescence (λem = 519 nm and Φ = 0.016) assigned to intraligand 3π-π* phosphorescence was observed for 1·H2O, whereas a stronger red emission ascribable to the phosphorescence from the triplet metal-metal-to-ligand charge transfer (3MMLCT) state was observed for the HCl adduct 1·HCl·nH2O (λem = 741 nm, Φ = 0.06 for n = 2, λem = 642 nm, and Φ = 0.10 for n = 6). Both complexes exhibited strong relative humidity (RH)-dependent proton conductivity, while surprisingly high conductivity was observed for 1·HCl (6.8 × 10-3 S cm-1) at 95% RH at 298 K. The reversible transformation between 1 and 1·HCl was achieved upon exposure to humid HCl gas and heating and their vapochromic behavior was completely different owing to the presence of acidic N-H protons and the addnl. hydrophilic Cl- counteranions in 1·HCl. To the best of the authors’ knowledge, these complexes are the first switchable vapochromic and highly proton conductive materials that can be employed to visualize the proton conducting state by color and luminescence.

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Application In Synthesis of Dichloro(1,5-cyclooctadiene)platinum(II). The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Mesoionic 1,2,3-Triazolo[1,5-a]pyridine-3-ylidenes in Phosphorescent Platinum(II) Complexes. Author is Soellner, Johannes; Strassner, Thomas.

Mesoionic carbene ligands based on 1,2,3-triazole platforms can be used in cyclometalated platinum(II) complexes to achieve an efficient phosphorescence even at room temperature In this report, 1,2,3-triazolo[1,5-a]pyridine-3-ylidenes are employed in such mols. along with β-diketonates with varying steric demand. For full structural characterization, NMR spectroscopy and XRD experiments were employed. The photophys. properties were studied in solid poly(Me methacrylate) (PMMA) matrixes, as well as dichloromethane solutions In PMMA, the synthesized complexes show quantum yields of 47-54% with emission bands in the yellow region of the visible spectrum. Cyclic voltammetry measurements along with DFT calculations helped to assign the nature of the observed emissions.

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Safety of Dichloro(1,5-cyclooctadiene)platinum(II). The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Confining the Inner Space of Strained Carbon Nanorings. Author is Grabicki, Niklas; Dumele, Oliver.

Strained aromatic macrocycles based on cycloparaphenylenes (CPPs) are the shortest repeating units of armchair single-walled carbon nanotubes. Since the development of several new synthetic methodologies for accessing these structures, their properties have been extensively studied. Besides the fundamental interest in these novel mol. scaffolds, their application in the field of materials science is an ongoing topic of research. Most of the reported CPP-type macrocycles display strong binding toward fullerenes, due to the perfect match between the convex and concave π-surfaces of fullerenes and CPPs, resp. Highly functionalized CPP derivatives capable of supramol. binding with other mols. are rarely reported. The synthesis of highly functionalized [ n]cyclo-2,7-pyrenylenes leads to CPP-type macrocycles with a defined cavity capable of binding non-fullerene guests with high association constants

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Recommanded Product: 12080-32-9. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Platinum Atoms Dispersed in Single-chain Polymer Nanoparticles. Author is Hu, Zhi-Yu; Pu, Hong-Ting; Wu, Jian-Guo.

The intramol. crosslinking of single polymer chains can form single-chain nanoparticles (SCNPs), which have many applications. In this study, styrenic copolymers with pendent triphenylphosphine as the coordination site for platinum ions (Pt(II)) and benzocyclobutene as the latent reactive groups are synthesized. Triphenylphosphine groups in the chains can coordinate Pt(II) and aid slight single-chain folding in dilute solution The intramol. crosslinking caused by the ring-open reaction of benzocyclobutene completes the single-chain collapse and forms stable SCNPs in dilute solution Pt(II) embedded in SCNPs can be further reduced to platinum atoms (Pt(0)). Pt(0) steadily and atomically dispersed in SCNPs exhibits better catalytic properties than normal polymer carried platinum particles do for the reduction of p-nitrophenol to p-aminophenol.

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Formula: C8H12Cl2Pt. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Efficient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine and its AgI, AuI and PtII complexes. Author is Rogovoy, Maxim I.; Davydova, Maria P.; Bagryanskaya, Irina Yu.; Artem’ev, Alexander V..

A convenient one-pot synthesis of diphenyl(pyrazin-2-yl)phosphine has been developed based on reaction of Ph3P with metallic lithium followed by treatment of the Ph2PLi formed with 2-chloropyrazine. The AgI, AuI and PtII chloride complexes derived from this phosphine have been synthesized and structurally characterized.

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Sutton, Ryan B.; Henderson, William published the article 《The water-solubilisation of the metalloligand [Pt2(μ2-S)2(PPh3)4] using 1,3,5-triaza-7-phospha-adamantane (PTA)》. Keywords: platinum triazaphosphaadamantane complex preparation stability ESI mass spectra.They researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).HPLC of Formula: 12080-32-9. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:12080-32-9) here.

The synthesis of the platinum(II) μ2-sulfide complex [Pt2(μ2-S)2(PTA)4] (PTA = phosphatriazaadamantane), as a water-soluble analog of the known triphenylphosphine complex [Pt2(μ2-S)2(PPh3)4], was explored through a range of synthetic routes. A direct synthesis, from cis-[PtCl2(PTA)2] and Na2S·9H2O in benzene is the most effective, while attempted ligand substitution of the PPh3 ligands of [Pt2(μ2-S)2(PPh3)4] with PTA resulted in rearrangement of the {Pt2S2} core, and formation of a series of PTA-substituted trinuclear species of the general composition [Pt3(μ3-S)2(PPh3)x(PTA)6-x]2+. The fully-substituted complex [Pt3(μ3-S)2(PTA)6]2+ was also obtained when cis-[PtCl2(PTA)2] was reacted with a sulfide ion-exchange resin. Reaction of [PtCl2(cod)] (cod = 1,5-cyclooctadiene) with Na2S·9H2O in benzene gave a red solid identified as crude [Pt2(μ2-S)2(cod)2]. Reaction of this labile {Pt2S2} precursor with PTA gave [Pt2(μ2-S)2(PTA)4] along with PTA -oxide and -sulfide. ESI mass spectrometry was widely employed as a convenient tool for exploring this chem., in conjunction with 31P{1H} NMR spectroscopy. These PTA-Pt-sulfide species, especially those containing {Pt2S2} cores, have a tendency to decompose in solution Addnl. confirmation of the formation of [Pt2(μ2-S)2(PTA)4] was provided by its reaction with [Rh2(μ2-Cl)2(cod)2], giving the adduct [Pt2(μ3-S)2(PTA)4Rh(cod)]+, identified using ESI MS.

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The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Platinum(II) Complexes with 10-(Aryl)phenoxarsines: Synthesis, Cis/Trans Isomerization, and Luminescence, the main research direction is platinum arylphenoxarsine complex preparation luminescence cis trans isomerism; frontier mol orbital platinum arylphenoxarsine complex; crystal structure platinum arylphenoxarsine complex.Name: Dichloro(1,5-cyclooctadiene)platinum(II).

Synthesis and structural and photophys. characterization of platinum dihalogenide complexes formulated as [PtHal2L2], where Hal = Cl and I, with different 10-(aryl)phenoxarsine ligands such as 10-(p-chlorophenyl)phenoxarsine, 10-(p-tolyl)phenoxarsine, and 10-(phenyl)phenoxarsine are reported. The structures of complexes were determined by NMR spectroscopy, mass spectrometry, and X-ray anal. Cis/trans isomerism of the complexes in solution was studied by NMR spectroscopy. In the solid state, under UV irradiation, platinum diiodide trans complexes exhibit an intense orange-red emission, which was attributed to a metal halide-centered triplet state. The UV/vis absorption and emission properties were studied and rationalized by d. functional theory (DFT) and time-dependent DFT calculations

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In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Synthesis and Photophysical Properties of Chalcophenes-Embedded Cycloparaphenylenes, published in 2019-05-03, which mentions a compound: 12080-32-9, mainly applied to chalcophenes cycloparaphenylene photophys property, Application In Synthesis of Dichloro(1,5-cyclooctadiene)platinum(II).

[N]Cyclo-4,4′-biphenylene-2”,5”-thienylenes ([n]CP2T, n = 3, 4), [n]cyclo-4,4′-biphenyl-ene-2”,5”-selenylenes ([n]CP2S, n = 3, 4), and [n]cyclo-4,4′-biphenylene-2”,5”-ethylenedioxythienylenes ([n]CP2E, n = 3) were synthesized in few steps with high overall yields. These nanorings were prepared through platinum-mediated cyclooligomerization of 2,5-bis(4-pinacolboryl-phenyl)chalcophenes. The X-ray crystallog. anal. of [4]CP2S showed that it employed a cone-shaped conformation in the solid state. Furthermore, their photophys. properties were investigated by using the UV-vis absorption spectra and fluorescence spectra. In particular, selenophene and 3,4-ethylenedioxythiophene-embedded cycloparaphenylenes, which showed significant red shifts in the UV-vis absorption and fluorescence spectra compared with thiophene analogs, are reported here for the first time.

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Name: Dichloro(1,5-cyclooctadiene)platinum(II). The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Zero-valent ML2 complexes of group 10 metals supported by terphenyl phosphines. Author is Martin, M. Trinidad; Marin, Mario; Rama, Raquel J.; Alvarez, Eleuterio; Maya, Celia; Molina, Francisco; Nicasio, M. Carmen.

Bulky terphenyl phosphine ligands PMe2Ar’ (Ar’ = terphenyl group) facilitate the isolation of zero-valent bis-phosphine complexes of Ni, Pd and Pt. The former show coordination numbers greater than two in the solid state due to the existence of Ni-Carene interactions with the terphenyl fragment.

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