Bioreduction of fluoroacetophenones by the fungi Aspergillus terreus and Rhizopus oryzae was written by Comasseto, Joao V.;Omori, Alvaro T.;Andrade, Leandro H.;Porto, Andre L. M.. And the article was included in Tetrahedron: Asymmetry in 2003.SDS of cas: 171032-87-4 This article mentions the following:
The enantioselective bioreduction of a number of fluoroacetophenones, e.g. I, was carried out with whole cells of Rhizopus oryzae CCT 4964, Aspergillus terreus CCT 3320 and Aspergillus terreus CCT 4083 giving the corresponding alcs. in good yield and high enantioselectivity. Initial results with these fungi indicated that some of them are promising biocatalysts for deracemization reactions of secondary alcs. In the experiment, the researchers used many compounds, for example, (S)-1-(2-Fluorophenyl)ethanol (cas: 171032-87-4SDS of cas: 171032-87-4).
(S)-1-(2-Fluorophenyl)ethanol (cas: 171032-87-4) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.SDS of cas: 171032-87-4
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts