Strunskaya, E. I. published the artcileElectrochemical Reduction and Oxidation of 3,4-Disubstituted 1,2,5-Thiadiazoles, Category: alcohols-buliding-blocks, the publication is Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii) (2003), 73(5), 806-815, database is CAplus.
The electron-acceptor N and S atoms in 3,4-disubstituted 1,2,5-thiadiazoles are responsible for much decreased reduction potentials and much increased oxidation potentials of these compounds compared with the corresponding carbocyclic derivatives The thiadiazole ring is resistant to oxidation, and the reversible electron transfer gives rise to fairly stable radical cations. Reductive stability of the heterocycle depends on the nature of its substituents and on the medium: when nucleophile substituents are present, 2-electron transfer in aprotic media results in heterocycle ring opening with iminonitrile formation, whereas in the presence of 2 readily leaving groups, the electron transfer induces cleavage of the complete heterocycle ring into inorganic anions.
Russian Journal of General Chemistry (Translation of Zhurnal Obshchei Khimii) published new progress about 30165-97-0. 30165-97-0 belongs to alcohols-buliding-blocks, auxiliary class Morpholine,Thiadiazole,Alcohol, name is 4-Morpholino-1,2,5-thiadiazol-3-ol, and the molecular formula is C6H8O6, Category: alcohols-buliding-blocks.
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