Savela, Risto’s team published research in Organometallics in 31 | CAS: 17877-23-5

Organometallics published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Category: alcohols-buliding-blocks.

Savela, Risto published the artcileIron-Catalyzed Chlorination of Silanes, Category: alcohols-buliding-blocks, the publication is Organometallics (2012), 31(8), 3199-3206, database is CAplus.

A simple and highly efficient Fe-catalyzed method for the chlorination of silanes was developed. Using 0.5-2% of the Fe(III)-based catalyst FeCl3 or Fe(acac)3 in the presence of 1-1.5 equiv of acetyl chloride as the Cl donor, a large number of silanes, alkoxysilanes, and silanols were converted to the corresponding chlorosilanes in 50-93% yields. In contrast to earlier reported methods often suffering from expensive catalysts or use of stoichiometric metal salts, hazardous reagents, and reaction conditions, the presently described methodol. allows benign reaction conditions and simple workup while using only catalytic amounts of a readily available and economically viable Fe catalyst.

Organometallics published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Category: alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts