Liang, Hao published the artcileSelective Electrochemical Hydrolysis of Hydrosilanes to Silanols via Anodically Generated Silyl Cations, Synthetic Route of 17877-23-5, the publication is Angewandte Chemie, International Edition (2021), 60(4), 1839-1844, database is CAplus and MEDLINE.
The first electrochem. hydrolysis of hydrosilanes to silanols under mild and neutral reaction conditions is reported. The practical protocol employs com. available and cheap NHPI as a hydrogen-atom transfer (HAT) mediator and operates at room temperature with high selectivity, leading to various valuable silanols in moderate to good yields. Notably, this electrochem. method exhibits a broad substrate scope and high functional-group compatibility, and it is applicable to late-stage functionalization of complex mols. Preliminary mechanistic studies suggest that the reaction appears to proceed through a nucleophilic substitution reaction of an electrogenerated silyl cation with H2O.
Angewandte Chemie, International Edition published new progress about 17877-23-5. 17877-23-5 belongs to alcohols-buliding-blocks, auxiliary class Protection and Derivatization Reagent, name is Triisopropylsilanol, and the molecular formula is C9H22OSi, Synthetic Route of 17877-23-5.
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