Wiensch, Eric M. published the artcileNickel-Catalyzed Amination of Silyloxyarenes through C-O Bond Activation, Category: alcohols-buliding-blocks, the publication is Angewandte Chemie, International Edition (2018), 57(34), 11045-11049, database is CAplus and MEDLINE.
Silyloxyarenes were utilized as electrophilic coupling partners with amines in the synthesis of aniline derivatives A diverse range of amine substrates were used, including cyclic or acyclic secondary amines, secondary anilines, and sterically hindered primary anilines. Addnl., a range of sterically hindered and unhindered primary aliphatic amines were employed, which have previously been challenging with other classes of aryl ether electrophiles. Orthogonal couplings of silyloxyarenes with aryl Me ethers are illustrated, where selectivity between the two C-O electrophiles is determined by ligand control, thereby allowing complementary and selective late-stage diversification of either electrophile. Finally, a sequential coupling displays the utility of this amination method along with the reversal in intrinsic reactivity between aryl Me ethers and silyloxyarenes.
Angewandte Chemie, International Edition published new progress about 27292-49-5. 27292-49-5 belongs to alcohols-buliding-blocks, auxiliary class Morpholine,Benzene,Phenol, name is 3-Morpholinophenol, and the molecular formula is C9H8BNO2, Category: alcohols-buliding-blocks.
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