Patel, Bhavesh H. published the artcileCommon origins of RNA, protein and lipid precursors in a cyanosulfidic protometabolism, Synthetic Route of 6346-09-4, the publication is Nature Chemistry (2015), 7(4), 301-307, database is CAplus and MEDLINE.
A minimal cell can be thought of as comprising informational, compartment-forming and metabolic subsystems. To imagine the abiotic assembly of such an overall system, however, places great demands on hypothetical prebiotic chem. The perceived differences and incompatibilities between these subsystems have led to the widely held assumption that one or other subsystem must have preceded the others. Here we exptl. investigate the validity of this assumption by examining the assembly of various biomol. building blocks from prebiotically plausible intermediates and one-carbon feedstock mols. We show that precursors of ribonucleotides, amino acids and lipids can all be derived by the reductive homologation of hydrogen cyanide and some of its derivatives, and thus that all the cellular subsystems could have arisen simultaneously through common chem. The key reaction steps are driven by UV light, use hydrogen sulfide as the reductant and can be accelerated by Cu(I)-Cu(II) photoredox cycling.
Nature Chemistry published new progress about 6346-09-4. 6346-09-4 belongs to alcohols-buliding-blocks, auxiliary class Amine,Aliphatic hydrocarbon chain,Ether, name is 4,4-Diethoxybutan-1-amine, and the molecular formula is C8H19NO2, Synthetic Route of 6346-09-4.
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