Gorb, L. G. published the artcileRelation between activity and selectivity in electrophilic substitution reactions of five-membered heteroaromatic compounds. 3. Electronic effects of substituents, Application In Synthesis of 17236-59-8, the publication is Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya (1983), 828-35, database is CAplus.
The activity and selectivity of the electrophilic reactions of monosubstituted benzenes, thiophenes, furans, and pyrrole were studied by calculating localization energies by the CNDO/2 MO method. Anal. of theor. and exptl. reactivity indexes indicated a difference in the transfer of substituent effects from the α and β positions of the 5-membered heterocycles. Orbital interactions must be calculated to explain the selectivity of electrophilic reactions of the 5-membered heterocycles.
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya published new progress about 17236-59-8. 17236-59-8 belongs to alcohols-buliding-blocks, auxiliary class Thiophene,Alcohol, name is Thiophen-3-ol, and the molecular formula is C4H4OS, Application In Synthesis of 17236-59-8.
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