Haque, Najirul published the artcileZn(II)-Embedded Nanoporous Covalent Organic Frameworks for Catalytic Conversion of CO2 under Solvent-Free Conditions, Recommanded Product: 3,5-Dimethylhex-1-yn-3-ol, the main research area is zinc embedded nanoporous covalent organic framework catalytic conversion CO2.
Covalent organic frameworks (COFs) have been gaining substantial attention over the past decade due to their developing crystalline porous polymeric nature linked by strong covalent bonds and widespread applications in various fields. Currently, three-dimensional COFs (3D COFs) are engaging the spotlight due to their distinctive porous features, greater surface area, and exceptional performances in comparison with formerly published two-dimensional (2D) frameworks with the AA-stacking layered mode. In this paper, we present, for the first time, a nanoporous 3D-COF-based zinc(II) catalyst (Zn@RIO-1), which shows an efficient pathway for the chem. conversion of carbon dioxide to produce α-alkylidene cyclic carbonates and oxazolidinones from propargylic alcs. The microporous material with a high surface area (312.61 m2/g) facilitates both types of catalytic reactions under atm. CO2 pressure. More importantly, easily recyclable and reusable catalysts produced moderate to high yields of desired carbonates as well as oxazolidinone products under solvent-free conditions. This study emphasizes the capability of nanoporous 3D-COF-based material in the catalysis field, more specifically in the field of CO2 capture and chem. fixation to fine chems. These results pave a spectacular pathway for the chem. fixation of CO2 into α-alkylidene cyclic carbonates and oxazolidinones from propargylic alcs. using 3D-COF as a potential heterogeneous ligand under sustainable conditions (i.e., solvent-free).
ACS Applied Nano Materials published new progress about Adsorption. 107-54-0 belongs to class alcohols-buliding-blocks, name is 3,5-Dimethylhex-1-yn-3-ol, and the molecular formula is C8H14O, Recommanded Product: 3,5-Dimethylhex-1-yn-3-ol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts