De Mesmaeker, Alain published the artcileStereoselective carbon-carbon bond formation in carbohydrates by radical cyclization reactions. I, Formula: C4H7BrO, the publication is Tetrahedron Letters (1988), 29(50), 6585-8, database is CAplus.
A 3 step synthesis of α-C(2) branched pyranosides from the glycal I is described. Thus, I was treated with HOCH2CH2Cl and BF3.Et2O in C6H6 to give 92% a mixture of α- and β-glycosides II in the ratio of 89:11 resp. On treatment with Bu3SnH and AIBN in C6H6 II cyclized stereoselectively to give predominately the α-C(2) branched pyranoside III.
Tetrahedron Letters published new progress about 50915-29-2. 50915-29-2 belongs to alcohols-buliding-blocks, auxiliary class Cyclopropanes, name is (1-Bromocyclopropyl)methanol, and the molecular formula is C4H7BrO, Formula: C4H7BrO.
Referemce:
https://en.wikipedia.org/wiki/Alcohol,
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