Gokel, George W.’s team published research in Tetrahedron Letters in | CAS: 73303-88-5

Gokel, George W. published the artcileSulfur heterocycles. I. Use of 4,4-dimethyl-1,3-oxathiolane-3,3-dioxide as a carbonyl anion equivalent, Recommanded Product: 2-Methyl-2-sulfanylpropan-1-ol, the publication is Tetrahedron Letters (1979), 3375-8, database is CAplus.

The oxathiolane I (R = H), acting as a carbonyl anion equivalent, was alkylated with BuLi and the appropriate reagent to give I [R = D, Me, PhCH₂, CH₂:CHCH₂, Me(CH₂)₅, 1-hydroxycyclopentyl, 1-hydroxycyclohexyl, 1-hydroxycyclododecyl, PhCH(OH), PhC(OH)Me, Me₃Si, Ph]. Thermal demasking of I (R ≠ H, D), with loss of Me₂C:CH₂ and SO₂, gave the corresponding aldehyde or α-silyl ketone. E.g., pyrolysis of I (R = PhCH₂) gave 100% PhCH₂CHO.

Tetrahedron Letters published new progress about 73303-88-5. 73303-88-5 belongs to alcohols-buliding-blocks, auxiliary class Thiol,Aliphatic hydrocarbon chain,Alcohol, name is 2-Methyl-2-sulfanylpropan-1-ol, and the molecular formula is C4H10OS, Recommanded Product: 2-Methyl-2-sulfanylpropan-1-ol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts