Du, Cheng published the artcileDirect Surface Modification of Graphitic C3N4 with Porous Organic Polymer and Silver Nanoparticles for Promoting CO2 Conversion, COA of Formula: C8H14O, the main research area is surface graphitic carbon nitride porous organic polymer silver nanoparticle.
The development of novel heterogeneous catalysts for converting CO2 into fine chems. under mild conditions is extremely attractive but challenging. In this study, graphitic carbon nitride modified by porous organic polymer (POP) and highly dispersed Ag nanoparticles (Ag/POP@g-C3N4) was prepared as a highly efficient heterogeneous catalyst for CO2 conversion for the first time. The POP modifying g-C3N4 remarkably increases sp. surface area and nitrogen species (N-H and C=N); as a result, the abundant porous structures together with anchoring sites allow tight immobilization and homogeneous dispersion of Ag nanoparticles. Benefiting from the effective incorporation, Ag/POP@g-C3N4 exhibited superior catalytic performance for the carboxylative cyclization of propargyl alcs. with CO2 under mild conditions. From the perspective of CO2 adsorption and controlled 1H NMR analyses, a plausible synergistic catalytic mechanism was proposed for the adsorption and activation of CO2 in combination with Ag/POP@g-C3N4 and 1,8-diazabicyclo[5.4.0]undec-7-chin (DBU). Constructing a heterogeneous catalyst by surface modification was proposed to efficiently promote green and sustainable conversion of CO2 into fine chems.
ACS Sustainable Chemistry & Engineering published new progress about Adsorption. 107-54-0 belongs to class alcohols-buliding-blocks, name is 3,5-Dimethylhex-1-yn-3-ol, and the molecular formula is C8H14O, COA of Formula: C8H14O.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts