Kou, Jinfang published the artcilePrecisely controlled Pd nanoclusters confined in porous organic cages for size-dependent catalytic hydrogenation, Formula: C8H14O, the main research area is palladium nanocluster preparation catalytic hydrogenation property.
The precise size-controlled formation of palladium (Pd) nanoclusters with size-dependent catalytic activity was achieved through a cage confinement strategy. In this process, three typical porous organic cages (POCs) with gradually decreasing cavity diameters were used as encapsulation carriers. A series of Pd nanoclusters-based catalysts with corresponding Pd cluster sizes of 0.73, 0.68, and 0.43 nm, resp., was effectively fabricated by confining the Pd nanoclusters in size-adjustable cavities. The obtained Pd@POCs nanocatalysts exhibited excellent crystallinity, high stability, fascinating morphol. characteristics, and superior catalytic hydrogenation performance. Especially, the size-dependent catalytic performance toward hydrogenation of 4-nitrophenol and semi-hydrogenation of alkyne compounds was demonstrated by exptl. results and theor. calculations The prepared Pd(1.71%)@FT-RCC3 catalyst with the smallest Pd cluster size of about 0.43 nm showed the best catalytic performance. This study promotes a better understanding of size-dependent catalysis and provides a new strategy for the fabrication of customized nanocatalysts.
Applied Catalysis, B: Environmental published new progress about Crystallinity. 107-54-0 belongs to class alcohols-buliding-blocks, name is 3,5-Dimethylhex-1-yn-3-ol, and the molecular formula is C8H14O, Formula: C8H14O.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts