Kartha, Ravindranathan K. P. published the artcileSimple and efficient strategy for making β-(1→6)-linked galactooligosaccharides using ‘naked’ galactopyranosides as acceptors, Computed Properties of 2595-07-5, the main research area is galactooligosaccharide beta linked preparation; galactopyranoside unprotected regioselective stereoselective glycosidation acetobromosugar.
Unprotected (naked) galactopyranosides were used for the first time in the direct regio- and stereoselective synthesis of β-(1→6)-linked oligosaccharides in 75-90% yield by coupling them with acetobromosugars in the presence of silver carbonate in dichloromethane. β-(1→4)-Linked oligosaccharides (yield 5-10%) were the byproducts. Thus, glycoside I (OSE = OCH2CH2SiMe3)was reacted with bromide II in the presence of Ag2CO3 in CH2Cl2 to give the disaccharide III (R = H).
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry published new progress about Glycosylation. 2595-07-5 belongs to class alcohols-buliding-blocks, name is (2R,3R,4S,5R,6R)-2-(Allyloxy)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol, and the molecular formula is C9H16O6, Computed Properties of 2595-07-5.
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