Total synthesis of the fungal metabolite (±)-acremine G: acceleration of a biomimetic Diels-Alder reaction on silica gel was written by Mehta, Goverdhan;Babu Khan, Tabrez;Sunil Kumar, Y. C.. And the article was included in Tetrahedron Letters in 2010.Recommanded Product: 52010-89-6 The following contents are mentioned in the article:
A total synthesis of the bioactive tetracyclic natural product acremine G has been achieved in which a regio- and stereoselective biomimetic Diels-Alder reaction between two readily assembled building blocks, accelerated on a solid support (silica gel), forms the key step. This study involved multiple reactions and reactants, such as 2,5-Dihydroxy-4-methylbenzaldehyde (cas: 52010-89-6Recommanded Product: 52010-89-6).
2,5-Dihydroxy-4-methylbenzaldehyde (cas: 52010-89-6) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Recommanded Product: 52010-89-6
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts