Tiollais, Rene’s team published research in Bulletin de la Societe Chimique de France in | CAS: 55376-31-3

Bulletin de la Societe Chimique de France published new progress about 55376-31-3. 55376-31-3 belongs to alcohols-buliding-blocks, auxiliary class Polymerization Reagents,ATRP Initiators, name is 2-Bromo-2-methylpropan-1-ol, and the molecular formula is C35H35ClN6O5, Application of 2-Bromo-2-methylpropan-1-ol.

Tiollais, Rene published the artcileSeveral physical and chemical properties of aliphatic enamines, Application of 2-Bromo-2-methylpropan-1-ol, the publication is Bulletin de la Societe Chimique de France (1964), 1205-6, database is CAplus.

RR’C:CHNR”2 prepared by known methods were [R, R’, NR”2, % yield, b.p. (mm.), density (temperature), and nD listed]: Me, H, NMe2, 33, 82° (760), 0.754 (23°), 1.4275; Et, H, NMe2 74, 107° (760), 0.768 (20°), 1.4345; Pr, H, NMe2, 79, 59° (60), 0.776 (20°), 1.4390; Am, H, NMe2, 71, 67° (15), 0.789 (20°), 1.4440; Et, H, NEt2, 53, 37° (12), 0.786 (22°), 1.4448; Am, H, NEt2, 57, 93° (13), 0.800 (16.8°), 1.4500; Et, H, NMeBu, 53, 65° (15), 0.786 (20.4°), 1.4492; Et, H, NMeBu-iso, 76, 82° (51), 0.779 (21°), 1.4460; Me, Me, NMe2, 64, 87° (760), 0.745 (19.6°), 1.4212; Me, Me, NEt2, 57, 57° (68), 0.761 (20°), 1.4268; Et, H, morpholino, 65, 72° (12), 0.935 (22°), 1.4750; Me, Me, morpholino, 61, 65° (18), 0.922 (20.4°), 1.4669. Bromination of the enamines in ether gave, after hydrolysis, α-bromo aldehydes (product, % yield, phys. properties, and m.p. 2,4-dinitrophenylhydrazone listed): 2-bromobutanal, 64, b25 42°, n21.5D 1.4595, d21.5 1.4531, 93-4°; 2-bromo-2-methylpropanol, 60, b70 47°, n21D 1.4522, d21 1.389, 115-16°; 2-bromoheptanal, 60, b12 80-1°, n22.5D 1.4621, d22.5 1.249, 105-6°.

Bulletin de la Societe Chimique de France published new progress about 55376-31-3. 55376-31-3 belongs to alcohols-buliding-blocks, auxiliary class Polymerization Reagents,ATRP Initiators, name is 2-Bromo-2-methylpropan-1-ol, and the molecular formula is C35H35ClN6O5, Application of 2-Bromo-2-methylpropan-1-ol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts