《Protonation-Triggered Supramolecular Gel from Macrocyclic Diacetylene: Gelation Behavior, Topochemical Polymerization, and Colorimetric Response》 was written by Shin, Geon; Khazi, Mohammed Iqbal; Kim, Jong-Man. Name: 3,5-Dihydroxybenzaldehyde And the article was included in Langmuir in 2020. The article conveys some information:
Herein, a novel supramol. gel was fabricated through the protonation-triggered unidirectional self-assembly of pyridine-attached macrocyclic diacetylene (PyMCDA). Basic nitrogen of a pyridine ring with a strong affinity toward proton transforms the neutral PyMCDA into gelator in its protonated pyridinium salt form (PyMCDA-H+), which further evolves to nano-fibrillar networks to yield a supramol. gel. Under the irradiation of UV light, the white color gel turned to a robust covalently cross-linked blue-phase PDA gel. Interestingly, polymeric PyMCPDA-H+ gel exhibits a naked-eye detectable reversible blue-red colorimetric response for alternating acid/base (H2SO4/NH4OH) and colorimetric sensitivity toward selected anions: CH3COO-, CN-, HCOO-, and CH3CH2COO-. It is with the hope that this work point toward the utility and versatility of macrocyclic PDAs for constructing chromogenic supramol. gels for their possible use in sensing systems. In addition to this study using 3,5-Dihydroxybenzaldehyde, there are many other studies that have used 3,5-Dihydroxybenzaldehyde(cas: 26153-38-8Name: 3,5-Dihydroxybenzaldehyde) was used in this study.
3,5-Dihydroxybenzaldehyde(cas: 26153-38-8) is a building block. It has been used in the synthesis of 2,4-dimethylbenzoylhydrazones with antileishmanial and antioxidant activities.Name: 3,5-Dihydroxybenzaldehyde
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts