Qiu, Chuntian; Sun, Yangyang; Xu, Yangsen; Zhang, Bing; Zhang, Xu; Yu, Lei; Su, Chenliang published their research in ChemSusChem in 2021. The article was titled 《Photoredox-Catalyzed Simultaneous Olefin Hydrogenation and Alcohol Oxidation over Crystalline Porous Polymeric Carbon Nitride》.HPLC of Formula: 100-55-0 The article contains the following contents:
Booming of photocatalytic water splitting technol. (PWST) opens a new avenue for the sustainable synthesis of high-value-added hydrogenated and oxidized fine chems., in which the design of efficient semiconductors for the in-situ and synergistic utilization of photogenerated redox centers are key roles. Herein, a porous polymeric carbon nitride (PPCN) with a crystalline backbone was constructed for visible light-induced photocatalytic hydrogen generation by photoexcited electrons, followed by in-situ utilization for olefin hydrogenation. Simultaneously, various alcs. were selectively transformed to valuable aldehydes or ketones by photoexcited holes. The porosity of PPCN provided it with a large surface area and a short transfer path for photogenerated carriers from the bulk to the surface, and the crystalline structure facilitated photogenerated charge transfer and separation, thus enhancing the overall photocatalytic performance. High reactivity and selectivity, good functionality tolerance, and broad reaction scope were achieved by this concerted photocatalysis system. The results contribute to the development of highly efficient semiconductor photocatalysts and synergistic redox reaction systems based on PWST for high-value-added fine chem. production The experimental part of the paper was very detailed, including the reaction process of 3-Pyridinemethanol(cas: 100-55-0HPLC of Formula: 100-55-0)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.HPLC of Formula: 100-55-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts