In 2019,Polymer included an article by Cao, Yufeng; Hu, Guangwei; Lin, Shaohui; Rempel, Garry L.; Pan, Qinmin. Electric Literature of C6H12O. The article was titled 《Synthesis of precisely diphenyl ether-functionalized polyethylene via acyclic diene metathesis polymerization》. The information in the text is summarized as follows:
We demonstrated the facile synthesis of a new class of functionalized polyethylene containing precisely sequenced di-Ph ether moieties via acyclic diene metathesis (ADMET) polymerization of a series of α, ω-diene monomers (M1-M3) with central di-Ph ether segments and subsequent exhaustive hydrogenation. 1H and 13C NMR spectroscopy have provided unambiguous evidence for precise primary architectures of the synthesized monomers and the resulting polymers. The thermal behaviors of all polymers were systematically investigated by thermogravimetric anal. (TGA) and differential scanning calorimetry (DSC). The results indicate that the introduction of di-Ph ether segments significantly enhanced the thermal stability of the polyethylenes. Ring-opening insertion metathesis polymerization (ROIMP) of M1-M3 with cis-cyclooctene was also performed, and after exhaustive hydrogenation, a series of irregularly sequenced copolymers with less regular chain structure and lower di-Ph ether content were yielded. Those copolymers possess a broad and ill-defined melting transition compared with the precisely-defined saturated homopolymers. In the part of experimental materials, we found many familiar compounds, such as 5-Hexen-1-ol(cas: 821-41-0Electric Literature of C6H12O)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Electric Literature of C6H12O
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