In 2018,Edelstein, Emma K.; Grote, Andrea C.; Palkowitz, Maximilian D.; Morken, James P. published ãA Protocol for Direct Stereospecific Amination of Primary, Secondary, and Tertiary Alkylboronic Estersã?Synlett published the findings.Electric Literature of C13H26B2O4 The information in the text is summarized as follows:
Primary, secondary, and (non-benzylic) tertiary alkylboronic acids underwent stereoselective (stereospecific) amination with O-methylhydroxylamine and potassium-tert-butoxide in toluene/THF to yield either Boc-protected primary or secondary amines or Boc-protected or free tertiary amines; nonracemic secondary and tertiary alkylamines were prepared in >98% enantiospecificities from the corresponding boronates.Bis[(pinacolato)boryl]methane(cas: 78782-17-9Electric Literature of C13H26B2O4) was used in this study.
Bis[(pinacolato)boryl]methane(cas: 78782-17-9) belongs to organoboron compounds. Organoboron compounds have been a cornerstone of synthetic transformations for decades. Areas such as boron-containing catalysts, metalate chemistry, photoredox methods, and boryl anions have brought significant new developments in understanding and provided new reactivity upon.Electric Literature of C13H26B2O4
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