In 2019,Dalton Transactions included an article by Wang, Danfeng; McBurney, Roy T.; Pernik, Indrek; Messerle, Barbara A.. Application of 100-55-0. The article was titled 《Controlling the selectivity and efficiency of the hydrogen borrowing reaction by switching between rhodium and iridium catalysts》. The information in the text is summarized as follows:
The catalytic alkylation of ketones with alcs. via the hydrogen borrowing methodol. (HB) has the potential to be a highly efficient approach for forming new carbon-carbon bonds. However, this transformation can result in more than one product being formed. The work reported here utilizes bidentate triazole-carbene ligated iridium and rhodium complexes as catalysts for the selective formation of alkylated ketone or alc. products. Switching from an iridium center to a rhodium center in the complex resulted in significant changes in product selectivity. Other factors – base, base loading, solvent and reaction temperature – were also investigated to tune the selectivity further. The optimized conditions were used to demonstrate the scope of the reaction across 17 ketones and 14 alcs. containing a variety of functional groups. A series of mechanistic investigations were performed to probe the reasons behind the product selectivity, including kinetic and deuterium studies. In the experimental materials used by the author, we found 3-Pyridinemethanol(cas: 100-55-0Application of 100-55-0)
3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. In industry and in the lab, pyridine is used as a reaction solvent, particularly when its basicity is useful, and as a starting material for synthesizing some herbicides, fungicides, and antiseptics.Application of 100-55-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts