《Effect of the distant substituent on the slow magnetic relaxation of the mononuclear Co(II) complex with pincer-type ligands》 was published in Dalton Transactions in 2020. These research results belong to Rajnak, Cyril; Titis, Jan; Moncol’, Jan; Boca, Roman. Name: 2,6-Pyridinedimethanol The article mentions the following:
A hexacoordinated complex [Co(pydm)2](mdnbz)2 from the family of pincer complexes was prepared and structurally characterized. The complex behaves as an S = 3/2 spin system with a considerable zero-field splitting parameter D/hc ~+50 cm-1. The a.c. susceptibility measurements show a slow magnetic relaxation with three relaxation channels: at the low-frequency (LF), intermediate-frequency (IF) and high-frequency (HF) domains. At T = 2.0 K and an external field BDC = 0.25 T, the relaxation times of the individual modes are τ(LF) = 282 ms, τ(IF) = 3.1 ms, and τ(HF) = 0.16 ms, and the mole fractions of the slowly relaxing species are x(LF) = 0.19, x(IF) = 0.45, and x(HF) = 0.37. A comparison with the analogous complex [Co(pydm)2](dnbz)2 possessing a demethylated counteranion and identical metal cation shows that even small modifications in the composition of SIMs are no longer underestimated for the slow magnetic relaxation. In addition to this study using 2,6-Pyridinedimethanol, there are many other studies that have used 2,6-Pyridinedimethanol(cas: 1195-59-1Name: 2,6-Pyridinedimethanol) was used in this study.
2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. Pyridines are often used as catalysts or reagents; particular notice has been paid recently to how pyridine coordinates to metal centers enabling a wide range of valuable reactions. Name: 2,6-Pyridinedimethanol
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