On April 30, 2022, Yu, Yi; Jiang, Yimin; Wu, Shaofen; Shi, Zhaojiang; Wu, Jinnan; Yuan, Yaofeng; Ye, Keyin published an article.Application In Synthesis of 1-Decanethiol The title of the article was Electrochemistry enabled selective vicinal fluorosulfenylation and fluorosulfoxidation of alkenes. And the article contained the following:
Both sulfur and fluorine play important roles in organic synthesis, the life science, and materials science. The direct incorporation of these elements into organic scaffolds with precise control of the oxidation states of sulfur moieties is of great significance. Herein, we report the highly selective electrochem. vicinal fluorosulfenylation and fluorosulfoxidn. reactions of alkenes, which were enabled by the unique ability of electrochem. to dial in the potentials on demand. Preliminary mechanistic investigations revealed that the fluorosulfenylation reaction proceeded through a radical-polar crossover mechanism involving a key episulfonium ion intermediate. Subsequent electrochem. oxidation of fluorosulfides to fluorosulfoxides were readily achieved under a higher applied potential with the adventitious H2O in the reaction mixture The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Application In Synthesis of 1-Decanethiol
The Article related to alkene thiol selective vicinal fluorosulfenylation fluorosulfoxidn electrochem, Placeholder for records without volume info and other aspects.Application In Synthesis of 1-Decanethiol
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