Xiao, Shuhuan; Liu, Chen; Song, Bin; Wang, Liang; Qi, Yan; Liu, Yongjun published the artcile< Samarium-based Grignard-type addition of organohalides to carbonyl compounds under catalysis of CuI>, Synthetic Route of 76-84-6, the main research area is alc ketone aldehyde preparation chemoselective; organohalide carbonyl compound Grignard addition copper catalysis.
Grignard-type additions were readily achieved under the mediation of CuI (10 mol%) and samarium (2 equivalent) by employing various organohalides, e.g. benzyl, aryl, heterocyclic and aliphatic halides (Cl, Br or I), and diverse carbonyl compounds (e.g. carbonic esters, carboxylic esters, acid anhydrides, acyl chlorides, ketones, aldehydes, propylene epoxides and formamides) to afford alcs., ketones and aldehydes, resp., with high efficiency and chemoselectivity, in which the organosamarium intermediate might be involved.
Chemical Communications (Cambridge, United Kingdom) published new progress about Addition reaction. 76-84-6 belongs to class alcohols-buliding-blocks, and the molecular formula is C19H16O, Synthetic Route of 76-84-6.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts