Product Details of 821-41-0In 2020 ,《Rhodium-Catalyzed Remote C(sp3)-H Borylation of Silyl Enol Ethers》 appeared in Angewandte Chemie, International Edition. The author of the article were Li, Jie; Qu, Shuanglin; Zhao, Wanxiang. The article conveys some information:
A rhodium-catalyzed remote C(sp3)-H borylation of silyl enol ethers (SEEs, E/Z mixtures) by alkene isomerization and hydroboration is reported. The reaction exhibits mild reaction conditions and excellent functional-group tolerance. This method is compatible with an array of SEEs, including linear and branched SEEs derived from aldehydes and ketones, and provides direct access to a broad range of structurally diverse 1,n-borylethers in excellent regioselectivities and good yields. These compounds are precursors to various valuable chems., such as 1,n-diols and amino alcs. The results came from multiple reactions, including the reaction of 5-Hexen-1-ol(cas: 821-41-0Product Details of 821-41-0)
5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Product Details of 821-41-0
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