Ota, Eisuke; Wang, Huaiju; Frye, Nils Lennart; Knowles, Robert R. published the artcile< A Redox Strategy for Light-Driven, Out-of-Equilibrium Isomerizations and Application to Catalytic C-C Bond Cleavage Reactions>, Synthetic Route of 167938-56-9, the main research area is light driven redox neutral isomerization cyclic aliphatic alc; linear carbonyl compound preparation out of equilibrium isomerization.
We report a general protocol for the light-driven isomerization of cyclic aliphatic alcs. to linear carbonyl compounds These reactions proceed via proton-coupled electron-transfer activation of alc. O-H bonds followed by subsequent C-C β-scission of the resulting alkoxy radical intermediates. In many cases, these redox-neutral isomerizations proceed in opposition to a significant energetic gradient, yielding products that are less thermodynamically stable than the starting materials. A mechanism is presented to rationalize this out-of-equilibrium behavior that may serve as a model for the design of other contrathermodynamic transformations driven by excited-state redox events.
Journal of the American Chemical Society published new progress about C-C bond cleavage (photo-). 167938-56-9 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H17NO3, Synthetic Route of 167938-56-9.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts