Yamamoto, Daisuke;Soga, Masayuki;Ansai, Hiromasa;Makino, Kazuishi published 《Manganese-catalysed hydroperoxidation of carbon-carbon double bonds using molecular oxygen present in air and hydroxylamine under ambient conditions》. The research results were published in《Organic Chemistry Frontiers》 in 2016.Recommanded Product: rel-(1R,2S)-1,2-Diphenylethane-1,2-diol The article conveys some information:
A highly efficient manganese-catalyzed hydroperoxidn. of carbon-carbon double bonds of enynes as well as styrene derivatives using N-hydroxyphthalimide, N-hydroxybenzotriazole or N-hydroxysuccinimide was developed. This reaction proceeded at room temperature through the direct incorporation of mol. oxygen present in air. The required catalytic loading of manganese(III) acetylacetonate was extremely low (generally 0.02-0.5 mol%, and a min. of 0.001 mol%). The experimental procedure involved many compounds, such as rel-(1R,2S)-1,2-Diphenylethane-1,2-diol (cas: 579-43-1) .
rel-(1R,2S)-1,2-Diphenylethane-1,2-diol(cas: 579-43-1 Recommanded Product: rel-(1R,2S)-1,2-Diphenylethane-1,2-diol) has been used in the preparation of trans-methyl meso-hydrobenzoin phosphite.
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