The preparation of ester heterocycles mostly uses heteroatoms as nucleophilic sites, which are achieved by intramolecular substitution or addition reactions. Compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ) is researched.HPLC of Formula: 12080-32-9.Soellner, Johannes; Strassner, Thomas published the article 《Mesoionic 1,2,3-Triazolo[1,5-a]pyridine-3-ylidenes in Phosphorescent Platinum(II) Complexes》 about this compound( cas:12080-32-9 ) in ChemPhotoChem. Keywords: crystal structure mol triazolopyridinylidene platinum diketone complex optimized DFT; uv vis photoluminescence phosphorescence triazolopyridinylidene platinum diketone complex redox. Let’s learn more about this compound (cas:12080-32-9).
Mesoionic carbene ligands based on 1,2,3-triazole platforms can be used in cyclometalated platinum(II) complexes to achieve an efficient phosphorescence even at room temperature In this report, 1,2,3-triazolo[1,5-a]pyridine-3-ylidenes are employed in such mols. along with β-diketonates with varying steric demand. For full structural characterization, NMR spectroscopy and XRD experiments were employed. The photophys. properties were studied in solid poly(Me methacrylate) (PMMA) matrixes, as well as dichloromethane solutions In PMMA, the synthesized complexes show quantum yields of 47-54% with emission bands in the yellow region of the visible spectrum. Cyclic voltammetry measurements along with DFT calculations helped to assign the nature of the observed emissions.
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