SDS of cas: 105-13-5. Recently I am researching about BIS(IMINO)PYRIDINE COBALT COMPLEXES; CHEMOSELECTIVE HYDROGENATION; IRON; EFFICIENT; SOLVENT; AMIDES; MILD; HYDROBORATION; ISOMERIZATION; INHIBITION, Saw an article supported by the CSIR, New DelhiCouncil of Scientific & Industrial Research (CSIR) – India [01(2942)/18/EMR-II]; MHRD; DST/INSPIRE fellowship [IF160793]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Singh, A; Maji, A; Joshi, M; Choudhury, AR; Ghosh, K. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol
Base-metal catalysts Co1, Co2 and Co3 were synthesized from designed pincer ligands L-1, L-2 and L-3 having NNN donor atoms respectively. Co1, Co2 and Co3 were characterized by IR, UV-Vis. and ESI-MS spectroscopic studies. Single crystal X-ray diffraction studies were investigated to authenticate the molecular structures of Co1 and Co3. Catalysts Col, Co2 and Co3 were utilized to study the dehydrogenative activation of alcohols for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines. Under optimized reaction conditions, a broad range of substrates including alcohols, anilines and ketones were exploited. A series of control experiments for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines were examined to understand the reaction pathway. ESI-MS spectral studies were investigated to characterize cobalt-alkoxide and cobalt-hydride intermediates. Reduction of styrene by evolved hydrogen gas during the reaction was investigated to authenticate the dehydrogenative nature of the catalysts. Probable reaction pathways were proposed for N-alkylation of amines, alpha-alkylation of ketones and synthesis of quinolines on the basis of control experiments and detection of reaction intermediates.
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Reference:
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