De Novo Asymmetric Bio- and Chemo-Catalytic Synthesis of Saccharides – Stereoselective Formal O-Glycoside Bond Formation Using Palladium Catalysis was written by Comely, Alex C.;Eelkema, Rienk;Minnaard, Adriaan J.;Feringa, Ben L.. And the article was included in Journal of the American Chemical Society in 2003.Quality Control of 3-(Hydroxymethyl)-4-nitrophenol This article mentions the following:
A novel integrated bio- and chemo-catalytic approach to the de novo catalytic asym. synthesis of saccharides has been developed. Acetoxypyranones obtained enantiopure by enzymic resolution have been shown to undergo highly stereoselective palladium-catalyzed formal O-glycoside bond formation. The combination of these protocols can be applied to asym. catalytic synthesis of saccharides. In the experiment, the researchers used many compounds, for example, 3-(Hydroxymethyl)-4-nitrophenol (cas: 60463-12-9Quality Control of 3-(Hydroxymethyl)-4-nitrophenol).
3-(Hydroxymethyl)-4-nitrophenol (cas: 60463-12-9) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Quality Control of 3-(Hydroxymethyl)-4-nitrophenol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts