Evaluation of Fe and Ru Pincer-Type Complexes as Catalysts for the Racemization of Secondary Benzylic Alcohols was written by Bornschein, Christoph;Gustafson, Karl P. J.;Verho, Oscar;Beller, Matthias;Baeckvall, Jan-E.. And the article was included in Chemistry – A European Journal in 2016.Recommanded Product: 120121-01-9 This article mentions the following:
Fe and Ru pincer-type catalysts are used for the racemization of benzylic alcs. Racemization with the Fe catalyst was achieved within 30 min. under mild reaction conditions, with a catalyst loading as low as 2 mol %. This reaction constitutes the first example of an iron-catalyzed racemization of an alc. The efficiency for racemization of the Fe catalyst and its Ru analog was evaluated for a wide range of sec-benzylic alcs. The com. available Ru complex proved to be highly robust and even tolerated the presence of water in the reaction mixture In the experiment, the researchers used many compounds, for example, (R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9Recommanded Product: 120121-01-9).
(R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Recommanded Product: 120121-01-9
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts