Modified Montmorillonite clay catalyzed regioselective ring opening of epoxide with amines and alcohols under solvent free conditions was written by Bhuyan, Diganta;Saikia, Lakshi;Dutta, Dipak Kumar. And the article was included in Applied Catalysis, A: General in 2014.Recommanded Product: Trans-2-(benzylamino)cyclohexanol This article mentions the following:
Modification of Montmorillonite by acid treatment depletes the layered structure and generates micro- and mesopores. The catalytic activity of naturally occurring Montmorillonite clay modified by acid treatment is reported for the reactions of epoxides with nucleophiles such as amines and alcs. at ambient temperature and solvent-free condition. The solid acid catalyst of the present study is reusable and exhibits significantly higher catalytic activities than known catalysts for the opening of the oxirane ring with nitrogen (aromatic as well as aliphatic amines) and oxygen (aromatic as well as aliphatic alcs.). A wide range of β-amino alcs. and β-alkoxy alcs. are synthesized with high epoxide conversion of excellent regioselectivity. The modified catalyst is recycled up to five times without significant loss in conversion and selectivity. In the experiment, the researchers used many compounds, for example, Trans-2-(benzylamino)cyclohexanol (cas: 40571-86-6Recommanded Product: Trans-2-(benzylamino)cyclohexanol).
Trans-2-(benzylamino)cyclohexanol (cas: 40571-86-6) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Recommanded Product: Trans-2-(benzylamino)cyclohexanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts