Phosphonate-containing polystyrene copolymer-supported Ru catalyst for asymmetric transfer hydrogenation in water was written by Xu, Xiao;Wang, Rui;Wan, Jingwei;Ma, Xuebing;Peng, Jingdong. And the article was included in RSC Advances in 2013.Name: (R)-1-(3-Chlorophenyl)ethanol This article mentions the following:
A series of phosphonate-containing polystyrene polymers with chiral ligand (1R,2R)-(+)-N1-toluenesulfonyl-1,2-diphenylethane-1,2-diamine were prepared by a radical copolymerization The supported ruthenium (Ru) catalysts displayed excellent catalytic performance (94-98% yield, 93.9-97.8% ee and 100% chemoselectivity) in an aqueous asym. transfer hydrogenation and the catalysts could be easily recycled by centrifugal separation The synthesis of the target compounds (catalysts) was achieved by a reaction of P-(1-phenylethenyl)phosphonic acid with monomers derived from (1R,2R)-1,2-diphenyl-1,2-ethanediamine and benzenesulfonamide and glycine or β-alanine. The title compounds thus formed included a β-alaninamide polymer (I). In the experiment, the researchers used many compounds, for example, (R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9Name: (R)-1-(3-Chlorophenyl)ethanol).
(R)-1-(3-Chlorophenyl)ethanol (cas: 120121-01-9) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Name: (R)-1-(3-Chlorophenyl)ethanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts