Diaw, A. K. D. published the artcileNew poly(p-substituted-N-phenylpyrrole)s. Electrosynthesis, electrochemical properties and characterization, Safety of 4-(1H-Pyrrol-1-yl)phenol, the publication is Synthetic Metals (2013), 74-85, database is CAplus.
Poly(N-p-hydroxyphenylpyrrole) [poly(HOPhPy)], poly(N-p-methoxyphenylpyrrole) [poly(MeOPhPy)], poly(N-p-thiophene-phenylpyrrole) [poly(ThPhPy)], poly(1,1′-phenylene dipyrridyl) [poly(PhDPy)] and poly(1,1′-diphenylene dipyrridyl) [poly(DPhDPy)] were electrosynthesized from the corresponding monomers on Pt electrode in 0.1 M tetrabutylammonium hexafluorophosphate (TBAPF6) acetonitrile solutions, using cyclic voltammetry (CV), galvanostatic and potentiostatic modes. The electrodeposited films were characterized by CV, FT-IR spectrometry, X-ray photoelectron spectra (XPS), and SEM. Electron-donating substituent effects on the polymer electrochem. properties were investigated by CV. The CV of the films indicated a good redox behavior and a peak position depending on the nature of substituent. FT-IR spectral studies allowed one to predict a linear and regular structure of the polymer chains, the coupling taking place in the 2 and 5 positions of the pyrrole rings. XPS anal. showed a variation of the film doping levels (26-42% for oxidized films and 6-12% for reduced films) with the electron-donor character of the Ph p-substituents. The conjugated π-electronic system was extended by strong electron-donating substituents which led to a higher doping level of the polypyrrolic chains and a polymer structure with high-energy and polar bonds like CN+ and CN+. SEM anal. revealed changes in the polymer film morphol. and thickness with the nature of substituents.
Synthetic Metals published new progress about 23351-09-9. 23351-09-9 belongs to alcohols-buliding-blocks, auxiliary class Pyrrole,Benzene,Alcohol, name is 4-(1H-Pyrrol-1-yl)phenol, and the molecular formula is C10H9NO, Safety of 4-(1H-Pyrrol-1-yl)phenol.
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