Zsabka, Peter published the artcileSelective extraction of trivalent actinides using CyMe4BTPhen in the ionic liquid Aliquat-336 nitrate, Name: n-Octanol, the main research area is trivalent actinide ionic liquid aliquat336 nitrate phase transfer catalyst.
The extraction of Am(III), Cm(III) and Eu(III) by 2,9-bis(5,5,8,8-tetramethyl-5,6,7,8-tetrahydro-1,2,4-benzotriazin-3-yl)-1,10-phenanthroline (CyMe4BTPhen) from nitric acid solution was studied using the ionic liquid Aliquat-336 nitrate ([A336][NO3]) as diluent. Results show a high selectivity of the solvent for Am(III) and Cm(III) over Eu(III), but rather slow extraction kinetics. The kinetics of CyMe4BTPhen were largely improved by the addition of 0.005 mol L-1N,N,N’,N’-tetra-n-octyl-diglycolamide (TODGA) as a phase transfer reagent and by the use of 1-octanol as co-diluent. The addition of the phase transfer catalyst and co-diluent did not compromise the selectivity towards the actinide/lanthanide separation and thus this four-component system can be successfully applied to sep. Am(III) and Cm(III) from the lanthanides.
RSC Advances published new progress about Ionic liquids. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Name: n-Octanol.
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