Karakas, Duygu Elma published the artcileKetone transfer hydrogenation reactions catalyzed by catalysts based on a phosphinite ligand, COA of Formula: C5H12O, the main research area is furanylethyldiphenylphosphinite preparation ruthenium iridium complexation; ketone transfer hydrogenation catalyzed furanylethyldiphenylphosphinite ruthenium iridium complex.
Reaction of (±)-1-(2-furyl)ethanol with an equivalent Ph2PCl in the presence of Et3N proceeds in dry toluene under an argon atm. to give 1-(furan-2-yl)ethyldiphenylphosphinite (1) in good yield. Mononuclear complexes [dichloro(η6-p-cymene)(1-furan-2-ylethyldiphenylphosphinite)ruthenium(II)] (2), [dichloro(η6-benzene)(1-furan-2-ylethyldiphenylphosphinite)ruthenium(II)] (3), [chloro(η4-1,5-cyclooctadiene)(1-furan-2-ylethyldiphenylphosphinite)rhodium(I)] (4) and [dichloro(η5-pentamethylcyclopentadienyl)(1-furan-2-ylethyldiphenylphosphinite)iridium(III)] (5) were synthesized and characterized by microanal., IR, MS, and NMR spectroscopies. The complexes are employed as catalysts in transfer hydrogenation of aromatic ketones. The complexes catalyzed reduction of a variety of aromatic ketone substrates bearing electron-withdrawing or donating substituents with very high conversion rates (up to 99%); 5 was the most efficient catalyst for the transfer hydrogenation of ketones.
Journal of Coordination Chemistry published new progress about Aryl ketones Role: RCT (Reactant), RACT (Reactant or Reagent). 584-02-1 belongs to class alcohols-buliding-blocks, name is 3-Pentanol, and the molecular formula is C5H12O, COA of Formula: C5H12O.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts