In 2019,Nature Catalysis included an article by Maity, Soham; Potter, Tyler J.; Ellman, Jonathan A.. Related Products of 821-41-0. The article was titled ãÎ?Branched amines by catalytic 1,1-addition of C-H bonds and aminating agents to terminal alkenesã? The information in the text is summarized as follows:
The convergent synthesis of α-branched amines e.g., I was achieved from three readily accessible starting materials: aromatic C-H bond substrates, terminal alkenes and aminating agents. This reaction proceeded by an intermol. formation of C-C and C-N bonds at the sp3 carbon branch site through an uncommon 1,1-alkene addition pathway. Ethylene and propylene feedstock chems. were effective alkene inputs, with ethylene in particular provided one-step synthesis of α-Me branched amines, a motif prevalent in drug structures. The reaction was scalable and 1% loading of an air-stable dimeric rhodium precatalyst was effective for several different types of products. The use of chiral catalysts also enabled the asym. synthesis of α-branched amines. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Related Products of 821-41-0)
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Related Products of 821-41-0
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts