ãHandy and highly efficient oxidation of benzylic alcohols to the benzaldehyde derivatives using heterogeneous Pd/AlO(OH) nanoparticles in solvent-free conditionsã?was published in Scientific Reports in 2020. These research results belong to Goksu, Haydar; Sen, Fatih. Electric Literature of C7H7BrO The article mentions the following:
The selective oxidation of benzylic alcs. was performed by using com. available aluminum oxy-hydroxide-supported palladium (Pd/AlO(OH)) nanoparticles (0.5 weight% Pd, about 3 nm size) under mild conditions. The oxidation method comprises the oxidation of benzyl alcs. catalyzed by aluminum oxy-hydroxide-supported palladium under ultrasonic and solvent-free conditions and a continuous stream of O2. The characterization of aluminum oxy-hydroxide-supported palladium nanocatalyst was conducted by several advanced anal. techniques including scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffraction (XRD), and elemental anal. by ICP-OES. The oxidation of a variety of benzyl alc. compounds were tested by the aluminum oxy-hydroxide-supported palladium nanoparticles, and all expected oxidation products were obtained by the high conversion yields within 3 h. The reaction progress was monitored by TLC (Thin-layer chromatog.), and the yields of the products were determined by 1H-NMR and 13C NMR anal. The experimental process involved the reaction of (4-Bromophenyl)methanol(cas: 873-75-6Electric Literature of C7H7BrO)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Electric Literature of C7H7BrO It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts