Sampson, Jessica; Bruening, Meaghan; Akhtar, Muhammed Naseem; Jaseer, E. A.; Theravalappil, Rajesh; Garcia, Nestor; Agapie, Theodor published their research in Organometallics in 2021. The article was titled 《Copolymerization of Ethylene and Long-Chain Functional α-Olefins by Dinuclear Zirconium Catalysts》.HPLC of Formula: 821-41-0 The article contains the following contents:
Bimetallic catalysts have shown promise for improving polar comonomer incorporation by late transition metals, but such effects are underexplored using early transition metal catalysts. Herein, the copolymerization of ethylene and α-olefins bearing alc. groups was performed using mono- and dizirconium bisamine bisphenolate catalysts in the presence of MAO and AliBu3. Under these conditions, catalyst activity was retained with comonomer incorporation trends mirroring those observed with unfunctionalized α-olefins, i.e., lower incorporation by bimetallic catalysts. Although incorporation levels are low, these data provide mechanistic insight for polar comonomer incorporation. These results are consistent with our earlier proposal that larger comonomers sterically clash with the distal metal center of the bimetallic catalysts, leading to lower incorporation. Addnl., a bimetallic mechanism for polar comonomer coordination and incorporation is not supported by the current data.5-Hexen-1-ol(cas: 821-41-0HPLC of Formula: 821-41-0) was used in this study.
5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.HPLC of Formula: 821-41-0
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