Xu, Xiangchao; Yang, Chenchen; Li, Shun; Meng, Chong; Yu, Junjie; Yang, Jiazhi; Li, Feng published an article in 2021. The article was titled 《From selective transfer hydrogenation to selective hydrogen auto-transfer process: An efficient method for the synthesis of alkenyl ketones via iridium-catalyzed α-alkylation of ketones with alkenyl alcohols》, and you may find the article in Journal of Catalysis.Safety of 5-Hexen-1-ol The information in the text is summarized as follows:
A strategy for the synthesis of alkenyl ketones via the α-alkylation of ketones with alkenyl ketones was proposed and accomplished. In the presence of a metal-ligand bifunctional catalyst [Cp*Ir(2,2′-bpyO)(H2O)], a series of desirable products were obtained in high yields. Mechanistic investigation revealed that functional groups in the ligand are crucial for the activity of catalyst and selective transfer hydrogenation is the determining step of the formation of alkenyl ketones as products. Notably, the present research exhibited also the unique potential of metal-ligand bifunctional catalysts for the activation of unsaturated alcs. as electrophiles for hydrogen auto-transfer process. In the part of experimental materials, we found many familiar compounds, such as 5-Hexen-1-ol(cas: 821-41-0Safety of 5-Hexen-1-ol)
5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Safety of 5-Hexen-1-ol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts