In 2019,Dalton Transactions included an article by Biswas, Nandita; Das, Kalicharan; Sardar, Bitan; Srimani, Dipankar. Reference of (4-Bromophenyl)methanol. The article was titled 《Acceptorless dehydrogenative construction of C=N and C=C bonds through catalytic aza-Wittig and Wittig reactions in the presence of an air-stable ruthenium pincer complex》. The information in the text is summarized as follows:
The construction of C=N bonds was achieved by the dehydrogenative coupling of alcs. ROH (R = CH2C6H5, CH(CH3)C6H5, thiophen-2-ylmethyl, etc.) and azides R1N3 (R1 = C6H5, CH2C6H5, 4-BrC6H4, etc.) via aza-Wittig type reaction. The reaction is catalyzed by an acridine-derived ruthenium pincer complex and does not use any oxidant. The present protocol offers a wide substrate scope, including aliphatic, aryl or heteroaryl alc./azides. This expeditious protocol was successfully applied to construct a C=C bond directly from alc. via dehydrogenative Wittig reaction. Furthermore, the synthesis of structurally important pyrrolo[1,4]benzodiazepine derivatives I and II was also achieved by this methodol. In addition to this study using (4-Bromophenyl)methanol, there are many other studies that have used (4-Bromophenyl)methanol(cas: 873-75-6Reference of (4-Bromophenyl)methanol) was used in this study.
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.Reference of (4-Bromophenyl)methanol It is used in the synthesis of amphiphilic, symmetric rod-coil, triblock copolymer of poly(9,9-didodecylfluorene-2,7-diyl) and poly(hydroxyl ethyl methacrylate)
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