On April 7, 2020, Joven-Sancho, Daniel; Baya, Miguel; Martin, Antonio; Orduna, Jesus; Menjon, Babil published an article.SDS of cas: 143-10-2 The title of the article was The First Organosilver(III) Fluoride, [PPh4][(CF3)3AgF]. And the article contained the following:
Organosilver(III) fluoride complexes have been assigned a key role in different fluorination processes. To the best of our knowledge, however, none of them seem to have been isolated or even detected thus far. Here we report on the successful synthesis of the trifluoromethyl derivative [PPh4][(CF3)3AgF], which has been isolated in high yield. The thermodn. stability of the Ag-F bond is shown by calculation and demonstrated by multistage mass spectrometry (MSn) under collision-induced dissociation (CID) conditions. Nevertheless, the substantial elongation found in the Ag-F bond (X-ray) is correlated with a marked nucleophilic character of the terminal F ligand. This Ag-F bond is, in fact, quite reactive: it suffers hydrolysis and is also solvolyzed by thiols. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).SDS of cas: 143-10-2
The Article related to crystal structure mol optimized organosilver fluoride preparation hydrolysis solvolysis, fluorides, high oxidation state, organosilver(iii), thiols, trifluoromethylation, Organometallic and Organometalloidal Compounds: Groups Ib, Iib – Cu, Ag, Au, Zn, Cd, Hg and other aspects.SDS of cas: 143-10-2
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