Zhao, Yao; Rui, Jiacheng; Du, Qiang; Chen, Rizhi; Zhan, Ying; Zheng, Xintao; Wu, Xiaojin published an article in 2021, the title of the article was Catalytic base-controlled regiodivergent heteronucleophilic hydrofunctionalization of β,γ-unsaturated amides.Category: alcohols-buliding-blocks And the article contains the following content:
A general catalytic base-controlled regiodivergent nucleophilic hydrofunctionalization of both terminal and internal β,γ-unsaturated amides has been reported. The atom-economical addition of various S/P-based nucleophiles was also exclusively chemoselective. More than 60 branched or linear hetero-substituted aliphatic amides were synthesized from common starting materials under transition-metal-free conditions. Preliminary mechanistic studies are consistent with proposed divergent catalytic cycles. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Category: alcohols-buliding-blocks
The Article related to branched linear hetero aliphatic amide preparation regioselective chemoselective, unsaturated amide thol phosphine oxide hydrothiolation hydrophosphinylation, Benzene, Its Derivatives, and Condensed Benzenoid Compounds: Amides, Amidines, Imidic Esters, Hydrazides, and Hydrazonic Esters and other aspects.Category: alcohols-buliding-blocks
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts