《Hypervalent Iodine(III)-Promoted Rapid Cascade Reaction of Quinoxalinones with Unactivated Alkenes and TMSN3》 was written by Shen, Jiabin; Xu, Jun; Huang, Lin; Zhu, Qing; Zhang, Pengfei. Product Details of 821-41-0 And the article was included in Advanced Synthesis & Catalysis in 2020. The article conveys some information:
The first example of rapidly three-component cascade reaction of quinoxalinones I (R1 = 6-OCH3, 6,7-(CH3)2, 7-Br, etc.; R2 = H, CH3, CH2C6H5, cyclohexylmethyl, etc.) with unactivated alkenes R3R4C=CHR5 (R3 = R4 = R5 = Me; R3 = n-Pr, R4 = R5 = H; R4 = H; R3R5 = -(CH2)4-, etc.) and TMSN3 under mild condition has been described. This approach provides a practical solution for the rapid modification of quinoxalinones and enables new planning strategies for the synthesis of bioactive organoazides II. A radical mechanism is responsible for this three-component transformation. In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Product Details of 821-41-0)
5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Product Details of 821-41-0
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