Name: 2,6-PyridinedimethanolIn 2019 ,《Unprecedented isolation of a dinuclear tin (II) complex stabilized by pyridine-2,6-dimethanol: structure, DFT and in vitro screening of cytotoxic properties》 appeared in Applied Organometallic Chemistry. The author of the article were I., Mantasha; Raza, Kausar Md.; Shahid, M.; Ansari, Azaj; Ahmad, Musheer; Khan, Ishaat M.. The article conveys some information:
The authors report a novel dinuclear Sn(II) complex, [Sn2(Hpdm)2(H2O)6]·2H2O 2Cl (1) (H2pdm (3) = pyridine-2,6-dimethanol), which was crystallized out and characterized by elemental anal., FTIR, 1H and 13C NMR, single crystal x-ray studies and D. Functional Theory (DFT) anal. X-ray structure of 1 confirmed it to be a dinuclear alkoxo-bridged Sn(II) species where each metal adopts a seven coordinate distorted pentagonal bipyramidal (pbp) geometry. This is the first heptacoordinated Sn(II) complex ever isolated apart from already reported stannylenes. Spin d. plots from DFT support the +2 oxidation state of each tin metal. Hirshfeld surface anal. reveals various H-bonding interactions in the mol. and mol. docking results along with DFT confirm higher binding affinity of the present complex towards DNA. Moreover, the complex exhibits promising anticancer activities against HeLa and A549 cancer cell lines. After reading the article, we found that the author used 2,6-Pyridinedimethanol(cas: 1195-59-1Name: 2,6-Pyridinedimethanol)
2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. The basicity and metallophilic high donor number of these π-deficient systems has long favored them as ligands in metal catalysis. The last decade saw pyridine assume a stronger role as functional group for directed C–H oxidation/activation.Name: 2,6-Pyridinedimethanol
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