Liu, Bin; Elder, W. Zachary; Miyake, Garret M. published the artcile< Scalable and Phosphine-Free Conversion of Alcohols to Carbon-Heteroatom Bonds through Blue-Light Promoted Iodination Reaction>, Reference of 699-12-7, the main research area is alc scalable carbon heteroatom bond blue light iodination.
A simple route toward the diverse conversion of alcs. via an SN2 pathway, in which blue light promoted iodination is used to form alkyl iodide intermediates from simple unreactive alcs. ROH [R = hex-5-yn-1-yl, 2-(1H-indol-3-yl)ethyl, cyclopentyl, etc.] was reported. The scope of the process tolerates a range of nucleophiles R1H [R1 = CN, (4-bromophenyl)carbonyloxidanyl, quinolin-6-yloxidanyl, (furan-2-yl)carbonyloxy, etc.] to construct C-N, C-O, C-S, and C-C bonds. Furthermore, this method can be used for the preparation and late stage functionalization of pharmaceuticals, as highlighted by the synthesis of thiocarlide, butoxycaine, and pramoxine.
Journal of Organic Chemistry published new progress about Alcohols Role: RCT (Reactant), RACT (Reactant or Reagent). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Reference of 699-12-7.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts